Mohamed, H., Elsayed, A., Abd el-latif, M., Mostafa, A. (2025). performance evaluation of half warm asphalt mixture prepared with natural and nano synthetic zeolite, chemical additives and polymers. JES. Journal of Engineering Sciences, 53(3), 111-126. doi: 10.21608/jesaun.2025.349056.1403
hussein Khaled Mohamed; Ahmed Abdelghani Elsayed; Mohamed El-shafie Abd el-latif; Abdelzaher Ezzeldeen Ahmed Mostafa. "performance evaluation of half warm asphalt mixture prepared with natural and nano synthetic zeolite, chemical additives and polymers". JES. Journal of Engineering Sciences, 53, 3, 2025, 111-126. doi: 10.21608/jesaun.2025.349056.1403
Mohamed, H., Elsayed, A., Abd el-latif, M., Mostafa, A. (2025). 'performance evaluation of half warm asphalt mixture prepared with natural and nano synthetic zeolite, chemical additives and polymers', JES. Journal of Engineering Sciences, 53(3), pp. 111-126. doi: 10.21608/jesaun.2025.349056.1403
Mohamed, H., Elsayed, A., Abd el-latif, M., Mostafa, A. performance evaluation of half warm asphalt mixture prepared with natural and nano synthetic zeolite, chemical additives and polymers. JES. Journal of Engineering Sciences, 2025; 53(3): 111-126. doi: 10.21608/jesaun.2025.349056.1403
performance evaluation of half warm asphalt mixture prepared with natural and nano synthetic zeolite, chemical additives and polymers
1Civil, faculty of engineering ,mataria,Helwan university , Ain shams , cairo
2civil engineering department faculty of engineering helwan university
3Applied Chemistry, Head of the Asphalt Laboratory, Egyptian Petroleum Research Institute, Nasr city , cairo
4Civil engineering, Matria school of engineering, helwan University
Abstract
Abstract This study evaluates the performance of Half Warm Mix Asphalt (HWMA) prepared with natural and nano synthetic zeolite, chemical additives, and polymers, aiming to develop an environmentally friendly alternative to conventional Hot Mix Asphalt (HMA). HWMA provides significant advantages, including reduced production temperatures and lower energy consumption, leading to decreased greenhouse gas emissions and improved worker safety. The research addresses the current gap in comparative analyses between HWMA and HMA by conducting comprehensive tests, including indirect tensile strength (ITS), loss of stability, and scanning electron microscope (SEM). The results demonstrated that HWMA modified with 10% synthetic zeolite, 5% epoxy, and 10% stearic acid achieved higher ITS values and reduced moisture susceptibility compared to conventional HMA. Notably, the inclusion of stearic acid at 90°C enhanced stability, resulting in a 9% reduction in stability loss when compared to the control sample. SEM analyses confirmed structural improvements and chemical interactions that contributed to enhanced performance. These findings highlight HWMA's potential as a sustainable and high-performance alternative to HMA without compromising mechanical properties.
[1] Eloufy, A. M., Abdelzaher, E. A. Mostafa, Ouf, M. S., & Ibrahim, M. F. (2022). Evaluating the Performance of Half Warm Asphalt Mixtures Using Reclaimed Asphalt Pavement (RAP). Port-Said Engineering Research Journal, 26(3), 56-64.
[2] Abdelzaher, E. A. Mostafa. (2016). Examining the performance of hot mix asphalt using nano-materials. IOSR Journal of Engineering (IOSRJEN), 6(02), pp. 25-34.
[3] Naser, A. M., Abd El-Wahab, H., Moustafa El Nady, M. A., Abdelzaher, E. A. Mostafa, Lin, L., & Sakr, A. G. (2019). Preparation and characterisation of modified reclaimed asphalt using nanoemulsion acrylate terpolymer. Pigment & Resin Technology, 48(5), 363-374.
[4] Wasiuddin, N. M., Selvamohan, S., Zaman, M. M., & Guegan, M. L. (2007). Comparative Laboratory Study of Sasobit and Aspha-Min Additives in Warm-Mix Asphalt. Transportation Research Record, 1998(1), 82-88.
[5] Eloufy, A. M., Abdelzaher, E. A. Mostafa, Ouf, M. S., & Ibrahimc, M. F. (2022). Investigating the Engineering Properties of Half-Warm Asphalt Mixes Using Chemical Additives. Egyptian International Journal of Engineering Sciences & Technology (EIJEST), 40, pp. 61-70.
[6] Autelitano, F., Garilli, E., & Giuliani, F. (2021). Half-warm mix asphalt with emulsion. An experimental study on workability and mechanical performances. Transportation Research Procedia, 55, 1081-1089.
[7] Arabani, M., & Hamedi, G. H. (2019). Laboratory study of the effect of natural zeolite on the behavioral properties of hot mix asphalt. Journal of Transportation, 16(1), pp. 321-336.
[8] El-Sayed, A. A., Mohamed, H. K., El-Latif, M. E., & Abdelzaher, E. A. Mostafa. (2024). Developing an Environmentally Friendly Semi Warm Asphalt Pavement Mix Using Polymers and Nanocomposite Materials. Engineering Research Journal, 183(3), 191-205.
[9] Abdelzaher, E. A. Mostafa. (2016). Development of Environmentally Sustainable Warm Mix Asphalt Using Sasobit and Nanomaterials. IOSR Journal of Engineering (IOSRJEN), 6(2), pp. 44-58.
[10] ASTM D5-06. (2006). Standard Test Method for Penetration of Bituminous Materials. American Association of State and Highway Transportation Officials, Washington, USA.
[11] ASTM D36-06. (2006). Standard Test Method for Softening Point of Bitumen (Ring-And-Ball Apparatus). American Association of State and Highway Transportation Officials, Washington, USA.
[12] ASTM D36-06. (2006). Standard Test Method for Viscosity Determination of Asphalt at Elevated Temperatures Using a Rotational Viscometer. American Association of State and Highway Transportation Officials, Washington, USA.
[13] Sengoz, B., Topal, A., Oner, J., Yilmaz, M., Dokandari, P. A., & Kok, B. V. (2017). Performance evaluation of warm mix asphalt mixtures with recycled asphalt pavement. Periodica Polytechnica Civil Engineering, 61(1), 117-127.
[14] Abdelzaher, E. A. Mostafa, Waleed, M.F. Tawhed, Mohamed, R. Elshahat. (2018). Developing New Design Criteria of Asphalt Pavement Mix Using Nano-Materials and Polymer-Materials. In Materials for Sustainable Infrastructure: Proceedings of the 1st GeoMEast International Congress and Exhibition, Egypt 2017 on Sustainable Civil Infrastructures 1 (pp. 335-347). Springer International Publishing.
[15] Kirdeciler, S. K. (2022). Synthesis of Zeolite 4A and Zeolite 13X from Locally Available Raw Materials by Thermal Activation Methods. Ph. D. thesis, Middle East Technical University (METU), Ankara, Turkey.
[16] Król, M. (2020). Natural vs. Synthetic zeolites. Crystals, 10(7), 622.
[17] Tawatwachoom, T., & Rungrojchaipon, P. (2015). In-Situ Synthesis of Zeolite A, Zeolite P and Zeolite Y/Carpon Composite with Carbonaceous Rice Husk Ash. Pure and Applied Chemistry International Conference 2015 (PACCON2015), Thailand Science Research and Innovation, Thailand.
[18] Polat, E., Karaca, M., Demir, H., & Onus, A. N. (2004). Use of natural zeolite (clinoptilolite) in agriculture. Journal of fruit and ornamental plant research, 12(1), 183-189.
[19] Ruíz-Baltazar, A., & Pérez, R. (2015). Kinetic adsorption study of silver nanoparticles on natural zeolite: experimental and theoretical models. Applied Sciences, 5(4), 1869-1881.
[20] Bunaciu, A. A., UdriŞTioiu, E. G., & Aboul-Enein, H. Y. (2015). X-ray diffraction: instrumentation and applications. Critical reviews in analytical chemistry, 45(4), 289-299.
[21] Ahel, M., & Giger, W. (1993). Aqueous solubility of alkylphenols and alkylphenol polyethoxylates. Chemosphere, 26(8), 1461-1470.
[22] European Union, EU. (2002). European Union Risk Assessment Report 4 Nonylphenol (Branched) and Nonylphenol. .2nd priority List, Volume 10.
[23] Seidel, A. (2004). Kirk-Othmer Encyclopedia of Chemical Technology. Hoboken, NJ, John Wiley & Sons, Inc.24:148.
[24] Energy Policy Act., EPA. (2009). Environmental Protection Agency. Washington DC- USA.
[25] Moezzi, A., McDonagh, A. M., & Cortie, M. B. (2012). Zinc oxide particles: Synthesis, properties and applications. Chemical engineering journal, 185, 1-22.
[26] Smijs, T. G., & Pavel, S. (2011). Titanium dioxide and zinc oxide nanoparticles in sunscreens: focus on their safety and effectiveness. Nanotechnology, science and applications, 95-112.
[27] Ruszkiewicz, J. A., Pinkas, A., Ferrer, B., Peres, T. V., Tsatsakis, A., & Aschner, M. (2017). Neurotoxic effect of active ingredients in sunscreen products, a contemporary review. Toxicology reports, 4, 245-259.
[28] Jiang, J., Pi, & Cai, J. (2018). The advancing of zinc oxide nanoparticles for biomedical applications. Bioinorganic chemistry and applications, 2018(1), 1062562.
[29] De Sousa Neto, V. F., Lucena, L. C. D. F. L., de Barros, A. G., Lucena, A. E. D. F. L., & Marinho Filho, P. G. T. (2022). Rheological evaluation of asphalt binder modified with zinc oxide nanoparticles. Case Studies in Construction Materials, 17, e01224.
[30] United States Pharmacopeia (2024). NF Monographs, Purified Stearic Acid. USP-NF. Rockville, MD: United States Pharmacopeia.
[31] The epoxy resin store. (2024). What is Epoxy Resin Used For?. Available at: https://www.theepoxyresinstore.com/, Last viewed on 17-9-2024.
[32] Naser, A., El-Wahab, A., El-Fattah, A., Abdelzaher, E. A. Mostafa, & Sakr, A. G. (2018). Preparation and characterization of modified reclaimed asphalt by using styrene–butyl acrylate nanoemulsion copolymer. Egyptian Journal of Chemistry, 61(2), 269-280.
[33] Naser, A. M., Abd El-Wahab, H., Moustafa El Nady, M. A., Abdelzaher, E. A. Mostafa, Lin, L., & Sakr, A. G. (2019). Preparation and characterisation of modified reclaimed asphalt using nanoemulsion acrylate terpolymer. Pigment & Resin Technology, 48(5), 363-374.
[34] AASHTO T-245. (2012). Standard Specifications for Transportation Materials and Methods of Sampling and Testing), “Part 2 tests, T-245”. American Association of State Highway and Transportation Officials, Washington, DC, USA.
[35] European Union, EU. (2002). European Union Risk Assessment Report 4 Nonylphenol (Branched) and Nonylphenol. .2nd priority List, Volume 10.
[36] Abdelzaher, E. A. Mostafa. (2005). The stripping susceptibility of airfield asphalt mixes: the development of guidelines for a laboratory test method, Ph. D. thesis, Carleton University, Ottawa, Canada.
[37] Kandil, K., Abd El Halim, A. O., Hassan, Y., & Mostafa, A. (2007). Investigation of the effects of different polymer-modified asphalt cements on asphalt mixes at low temperature. Canadian Journal of Civil Engineering, 34(5), 589-597.
[38] Eloufy, A. M. (2019). Developing an Environmental Friendly Sustainable Half Warm Asphalt Mix Using Recycled Materials. Ph. D. thesis. Helwan University, Egypt.
[39] Al-Qudah, A. H., Koting, S., Ibrahim, M. R., Alibrahim, M., & Jegatheesan, N. (2024). Resistance of Rubberized Asphalt Mixture to Aging and Moisture Damage. IIUM Engineering Journal, 25(2), 130-147.
[40] Mohammed, A., Avin Abdullah, A. (November, 2019). Scanning Electron Microscopy (SEM): A Review. Proceedings of 2018 International Conference on Hydraulics and Pneumatics – HERVEX, November 7-9, Băile Govora, Romania.
[41] Mimura, H., Yokota, K., Akiba, K., & Onodera, Y. (2001). Alkali hydrothermal synthesis of zeolites from coal fly ash and their uptake properties of cesium ion. Journal of nuclear Science and Technology, 38(9), 766-772.
[42] Mazumder, M., Ahmed, R., Ali, A. W., & Lee, S. J. (2018). SEM and ESEM techniques used for analysis of asphalt binder and mixture: A state of the art review. Construction and Building Materials, 186, 313-329.
View on SCiNiTO
Top